What's the difference among RLS, permission, access settings?

I will go in rever order
Acess is for access level on Workspace, who can manage, contribute to the workspace (Admin/Developers), it applies at workspace level Roles in the new workspaces in Power BI - Power BI | Microsoft Docs 

Permission - What type to permissions user/group have - Read/reshare, it is at dataset/report level Manage dataset access permissions - Power BI | Microsoft Docs

RLS- This is applicable at dataset level to determine what data will be visible to users based on there acess level. This applys when shared through APP. Row-level security (RLS) with Power BI - Power BI | Microsoft Docs